N-(2-Thienylmethylene)naphthalen-1-amine

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N-(2-Thienylmethyl­ene)naphthalen-1-amine

In the title compound, C(15)H(11)NS, the dihedral angle between the thio-phene and 1-naphthyl rings is 31.42 (11)°. The mol-ecule adopts a trans configuration about the central C=N bond. In the crystal, the mol-ecules are connected via weak C-H⋯π inter-actions.

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N-(Prop-2-yn-1-yl)-1,3-benzothia­zol-2-amine

In the title compound, C(10)H(8)N(2)S, the 2-amino-benzothia-zole and propyne groups are not coplanar [dihedral angle = 71.51 (1)°]. The crystal structure is stabilized by strong inter-molecular N-H⋯N hydrogen bonds and C-H⋯C, C-H⋯π and F-type aromatic-aromatic [centroid-centroid distance = 3.7826 (12) Å] inter-actions are also observed.

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N-Benzyl­pyridin-2-amine

In the crystal of the title compound, C(12)H(12)N(2), inter-molecular N-H⋯N hydrogen bonds form rings of graph-set motif R(2) (2)(8) and C-H⋯π inter-actions further consolidate the dimers. Neighbouring dimers are further connected into a three-dimensional network by C-H⋯π inter-actions. The benzyl and pyridyl rings form a dihedral angle of 67.2 (1)°

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N-(2-aminobenzyl)-N,N-bis(quinolin-2-ylmethyl)amine.

The title new diquinaldine derivative, C27H24N4, forms molecular assemblies organized by intermolecular quinoline pi-pi stacking [3.356 (3) and 3.440 (3) A] and both inter- and intramolecular N-H...N hydrogen bonds [3.039 (3)-3.104 (3) A and 129 (2)-172 (2) degrees]. The combination of such interactions provides readily definable contacts that propagate along each crystallographic axis.

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N,N′-(4-Chloro­benzyl­idene)dipyrimidin-2-amine

The title compound, C(15)H(13)ClN(6), contains two pyrimidine rings and one benzene ring, where the dihedral angle between the planes through the pyrimidine rings is 81.57 (10)°, and those between the pyrimidine rings and the benzene ring are 84.02 (8) and 89.46 (7)°, indicating that the three rings are almost perpendicular. In the crystal, inter-molecular N-H⋯N hydrogen bonds link the mol-ecul...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809041774